Quartz

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Quartz
Quartz crystal group from Arkansas
General
Category	Mineral
Chemical formula	Silica (silicon dioxide, SiO2)
Identification
Color	Clear (if no impurities); also see Varieties
Crystal habit	6-sided prism ending in 6-sided pyramid (typical)
Crystal system	rhombohedral class 32
Twinning	Dauphine law, Brazil law and Japan law
Cleavage	None
Fracture	Conchoidal
Mohs Scale hardness	7 - lower in impure varieties
Luster	Vitreous/glossy
Refractive index	nω = 1.543 - 1.545 nε = 1.552 - 1.554
Optical Properties	Uniaxial (+)
Birefringence	+0.009 (B-G interval)
Pleochroism	None
Streak	White
Specific gravity	2.65 constant; variable in impure varieties
Melting point	1650 (±75) °C
Solubility	11.0 +/- 1.1 PPM @ 25 C
Diaphaneity	Transparent to translucent
Other Characteristics	Piezoelectric

Quartz (from German Quarz (help·info)^[1]) is the most abundant mineral in the Earth's continental crust (although feldspar is more common in the world as a whole). It is made up of a lattice of silica (SiO₂) tetrahedra. Quartz has a hardness of 7 on the Mohs scale and a density of 2.65 g/cm³.

[edit] Crystal habit

Quartz belongs to the rhombohedral crystal system. The ideal crystal shape is a six-sided prism terminating with six-sided pyramids at each end. In nature quartz crystals are often twinned, distorted, or so intergrown with adjacent crystals of quartz or other minerals as to only show part of this shape, or to lack obvious crystal faces altogether and appear massive. Well-formed crystals typically form in a 'bed' that has unconstrained growth into a void, but because the crystals must be attached at the other end to a matrix, only one termination pyramid is present. A quartz geode is such a situation where the void is approximately spherical in shape, lined with a bed of crystals pointing inward.

[edit] Varieties

Pure quartz is colorless or white; common colored varieties include rose quartz, amethyst, smoky quartz, milky quartz, and others. Quartz goes by an array of different names. The most important distinction between types of quartz is that of macrocrystalline (individual crystals visible to the unaided eye) and the microcrystalline or cryptocrystalline varieties (aggregates of crystals visible only under high magnification). Chalcedony is a generic term for cryptocrystalline quartz. The cryptocrystalline varieties are either translucent or mostly opaque, while the transparent varieties tend to be macrocrystalline.

Citrine

Citrine is a variety of quartz. It ranges in color from a pale yellow to brown. Citrine has ferric impurities, and is rarely found naturally. Most commercial citrine is in fact artificially heated amethyst or smoky quartz. Brazil is the leading producer of citrine, with much of its production coming from the state of Rio Grande do Sul.

Citrine

Citrine is one of three traditional birthstones for the month of November.

It is nearly impossible to tell cut citrine from yellow topaz visibly.

Rose Quartz

An elephant carved in rose quartz, 4 inches (10 cm) long

Rose quartz is a type of quartz which exhibits a pale pink to rose red hue. The color is usually considered as due to trace amounts of titanium, iron, or manganese, in the massive material. Some rose quartz contains microscopic rutile needles which produces an asterism in transmitted light. Recent X-ray diffraction studies suggest that the color is due to thin microscopic fibers of possibly dumortierite within the massive quartz.^[2]

Milk quartz sample

Milk quartz or milky quartz may be the most common variety of crystalline quartz and can be found almost anywhere. The white colour may be caused by minute fluid inclusions of gas and/or liquid trapped during the crystal formation. The cloudiness caused by the inclusions effectively bars its use in most optical and quality gemstone applications.^[3]

In crystal form (rarely found) it is called pink quartz and its color is thought due to trace amounts of phosphate or aluminium. The color in crystals is apparently photosensitive and subject to fading. The first crystals were found in a pegmatite found near Rumford, Maine, USA, but most crystals on the market come from Minas Gerais, Brazil.^[4]

Rose Quartz is not popular as a gem; the mineral is generally too cloudy and not clear enough to be cut into a gem. Very rarely, some rose quartz is suitable. Rose Quartz is more often carved into figures such as people or hearts. Hearts are commonly found because Rose Quartz is pink and an affordable mineral.

Although many of the varietal names historically arose from the color of the mineral, current scientific naming schemes refer primarily to the microstructure of the mineral. Color is a secondary identifier for the cryptocrystalline minerals, although it is a primary identifier for the macrocrystalline varieties. This does not always hold true.

Tiger's eye	Rose quartz	Milk quartz	Rutilated quartz crystal
Smoky quartz	Quartz sand from Coral Pink Sand Dunes State Park, Utah. These have a hematite coating which provides the orange color. Scale bar is 1.0 mm.

[edit] Synthetic and artificial treatments

A synthetic quartz crystal grown by the hydrothermal method, about 19 cm long and weighing about 127 grams.

Not all varieties of quartz are naturally occurring. Prasiolite, an olive colored material, is produced by heat treatment; natural prasiolite has also been observed in Lower Silesia in Poland. Although citrine occurs naturally, the majority is the result of heat-treated amethyst. Carnelian is widely heat-treated to deepen its color.

Due to natural quartz being so often twinned, much of the quartz used in industry is synthesized. Large, flawless and untwinned crystals are produced in an autoclave via the hydrothermal process; emeralds are also synthesized in this fashion. While these are still commonly referred to as quartz, the correct term for this material is silicon dioxide.

[edit] Occurrence

Quartz occurs in hydrothermal veins and pegmatites. Well-formed crystals may reach several meters in length and weigh hundreds of kilograms. These veins may bear precious metals such as gold or silver, and form the quartz ores sought in mining. Erosion of pegmatites may reveal expansive pockets of crystals, known as "cathedrals."

Quartz is a common constituent of granite, sandstone, limestone, and many other igneous, sedimentary, and metamorphic rocks.

[edit] Related silica minerals

Tridymite and cristobalite are high-temperature polymorphs of SiO₂ that occur in high-silica volcanic rocks. Coesite is a denser polymorph of quartz found in some meteorite impact sites and in metamorphic rocks formed at pressures greater than those typical of the Earth's crust. Stishovite is a yet denser and higher-pressure polymorph of quartz found in some meteorite impact sites. Lechatelierite is an amorphous silica glass SiO₂ which is formed by lightning strikes in quartz sand.

[edit] History

Quartz crystal showing transparency.

The name "quartz" comes from the German "Quarz", which is of Slavic origin (Czech miners called it křemen). Other sources insist the name is from the Saxon word "Querkluftertz", meaning cross-vein ore.^[5]

Quartz is the most common material identified as the mystical substance maban in Australian Aboriginal mythology. It is found regularly in passage tomb cemeteries in Europe in a burial context, eg. Newgrange or Carrowmore in the Republic of Ireland. The Irish word for quartz is grian cloch, which means 'stone of the sun'.

Roman naturalist Pliny the Elder believed quartz to be water ice, permanently frozen after great lengths of time. (The word "crystal" comes from the Greek word for purity.) He supported this idea by saying that quartz is found near glaciers in the Alps, but not on volcanic mountains, and that large quartz crystals were fashioned into spheres to cool the hands. He also knew of the ability of quartz to split light into a spectrum. This idea persisted until at least the 1600s.

In the 17th century, Nicolas Steno's study of quartz paved the way for modern crystallography. He discovered that no matter how distorted a quartz crystal, the long prism faces always made a perfect 60 degree angle.

Charles Sawyer invented the commercial quartz crystal manufacturing process in Cleveland, Ohio, United States. This initiated the transition from mined and cut quartz for electrical appliances to manufactured quartz.

Quartz's piezoelectric properties were discovered by Jacques and Pierre Curie in 1880. The quartz oscillator or resonator was first developed by Walter Guyton Cady in 1921.^[6] George Washington Pierce designed and patented quartz crystal oscillators in 1923.^[7] Warren Marrison created the first quartz oscillator clock based on the work of Cady and Pierce in 1927.^[8]

[edit] Piezoelectricity

Quartz crystals have piezoelectric properties, that is they develop an electric potential upon the application of mechanical stress. An early use of this property of quartz crystals was in phonograph pickups. One of the most common piezoelectric uses of quartz today is as a crystal oscillator. The quartz clock is a familiar device using the mineral. The resonant frequency of a quartz crystal oscillator is changed by mechanically loading it, and this principle is used for very accurate measurements of very small mass changes in the quartz crystal microbalance and in thin-film thickness monitors.

[edit] See also

Wikisource has original text related to this article:

EB1911:Quartz

• Fused quartz
• List of minerals
• Shocked quartz
• Quartz reef mining

[edit] Notes

[edit] References

Wikimedia Commons has media related to: Quartz

• Hurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, 20th ed., ISBN 0-471-80580-7
• Quartz varieties, properties, crystal morphology. Photos and illustrations
• Arkansas quartz, Rockhounding Arkansas
• Gilbert Hart Nomenclature of Silica, American Mineralogist, Volume 12, pages 383-395, 1927
• Queensland University of Technology Origin of the word quartz.
• PDF of Charles Sawyer's cultured quartz process description
• Smithsonian Institute, Inventors of quartz oscillating devices
• Terminology used to describe the characteristics of Quartz Crystals when used as oscillators